First half ended scoreless but was played on the edge and referee Daniele Orsato produced five yellow cards.
Kylian Mbappe was presented with golden opportunity to break deadlock but fired his shot into side-netting.
Jesse Lingard and Anthony Martial were both forced off with injuries as United were hit with double blow.
Presnel Kimpembe converted Angel Di Maria's cross to score his first goal for PSG and give them the lead.
PSG then doubled their advantage seven minutes later as Mbappe opened his body up to slot home.
Paul Pogba was sent off late in game after receiving second yellow card to add insult to injury.
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