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Defeat felt inevitable as soon as City scored their second goal, and Chris Wilder's side remain bottom of the table, and without an away win this season.
De Bruyne's intelligent movement and use of the ball was central to aCity side that looked sharper and hungrier than the hosts, andit was the Belgium international's work that created a second goal for City after 35 minutes.
City were back in it in the 69th minute when substitute Aguero saw a shot come back off Jay Fulton's face and the Argentina striker subsequently teed up Silva for a fine outside-of-the-foot finish.
City seemed on course for a customary home win against West Brom when Ilkay Gundogan applied a first-time finish to Raheem Sterling's cutback after half an hour.
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The goal came late in the game to maintain the perfect home record of Unai Emery's side and reflected their superior endeavour throughout the contest against an unusually passive City.
After Kevin de Bruyne gave Pep Guardiola's side an early lead it looked like they would go on to claim a big win as the hosts barely laid a glove on them.
This was not so much a victory as an evisceration. It was not so much a defeat as a demolition. Manchester City returned to the top of the Premier League, with another Sergio Aguero hat-trick, and did so by destroying Chelsea.
Holding a 2-1 lead from the first leg, City found themselves needing to chase the tie when 17-year-old England international Jude Bellingham curled in a superb shot from the edge of the box.