The Super Falcons' captain netted her first goal in the 43rd minute and she scored the second immediately after the resumption for the second half.
Jennifer Hermoso increased the scoreline to 3-0 in the 73rd minute while Aitana Bonmati made the victory emphatic by scoring the fourth goal in the 87th minute.
Barcelona have now extended their winning streak to seven matches in all competitions and are topping the Spanish Primera Iberdrola after seven games played this term.
Oshoala on the other hand has now scored eight goals for Barcelona this season in all competitions.
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